Should New Disruptive Technologies be Used for Classification in Ancient Linnaean Rankings

We can do experiments to objectively decide species? Certainly we have some guidelines (reproductive isolation being the most commonly stated), but where do we draw the line between Carolina Chickadee and Black-capped Chickadee? Or Florida Cottonmouth and Northern Cottonmouth? These aren’t reproductively separated (nor are they geographically separated at their hybrid zones).