Mythbusters had an episode about if tomato juice removes skunk spray. It doesn’t, not very well. Water is also bad, it activates the scent. A mix of 1 quart 3% hydrogen peroxide, a quarter cup of baking soda, and 1-2 tablespoons liquid soap works best, out of the things they tried.
Never been personally sprayed, but if anyone trips over this thread looking for advice, hopefully that can help them. Again: WATER MAKES IT WORSE. Don’t try to wash it off with water. Tomato juice isn’t very effective, but may help a little since it’s acidic.
(I did stink up our backyard with a roadkill skunk, once. I wanted to see if it was fresh enough to skin. It was not. I had wind blowing in my face as I was bringing it from the road to the yard, so I didn’t realize it was not-fresh until I got into the yard and the wind stopped. We quadruple-bagged it and the trash can still reeked for months afterward. Skunk spray and rot is a bad combination.)